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History and Production
From the Latin word rubidus, deepest red. It was discovered by R.W. Bunsen and G.R. Kirchhoff in 1861 from the mineral lepidolite by means of spectroscopy. The name rubidium was derived
due to the deep red line shown in the spectra. It can be commercially recovered from lepidolite. It can also be extracted from potassium minerals. At present, there is little industrial use of the element.
It is used as a getter in vacuum tubes and as a photocell component.
Physical Data
It is a soft, silvery-white metal. No rubidium mineral is found in nature, but it is usually associated with the lithium mineral lepidolite. Rubidium compound gives a yellowish violet color in flame.
Interatomic distance: 495 pm
Melting point: 39.31°C
Boiling point: 688°C
Thermal conductivity/Wm-1K-1: 58.2 (27°C)
Density/kgm-3: 1532 (20°C), 1475 (m.p.)
Standard Thermodynamic Data (atomic gas)
Enthalpy of formation: 80.9 kJ/mol
Gibbs free energy of formation: 53.1 kJ/mol
Entropy: 170.1 J/mol K
Heat capacity: 20.8 J/mol K
Electronic data
Electronic configuration: [Kr] 5s1
Term symbol: 2S1/2
Electron affinity: 46.8842 kJ/mol Electronegativity (Pauline): 0.82
Ionization energy (first, second, third): 403.032, 2632.60, 3859.42 kJ/mol
Chemical properties
It is very reactive that ignites spontaneously in air and violently in water to give rubidium hydroxide.
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